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41.
The Mordor Alkaline Igneous Complex (MAIC) is a composite intrusion comprising a body of syenite and a funnel-shaped layered
mafic–ultramafic intrusion of lamprophyric parentage, the Mordor Mafic–Ultramafic Intrusion or MMUI. The MMUI is highly unusual
among intrusions of lamprophyric or potassic parentage in containing primary magmatic platinum-group element (PGE)-enriched
sulfides. The MMUI sequence consists largely of phlogopite-rich pyroxenitic cumulates, with an inward dipping conformable
layer of olivine-bearing cumulates divisible into a number of cyclic units. Stratiform-disseminated sulfide accumulations
are of two types: disseminated layers at the base of cyclic units, with relatively high PGE tenors; and patchy PGE-poor disseminations
within magnetite-bearing upper parts of cyclic units. Sulfide-enriched layers at cycle bases contain anomalous platinum group
element contents with grades up to 1.5 g/t Pt+Pd+Au over 1-m intervals, returning to background values of low parts per billion
(ppb) on a meter scale. They correspond to reversals in normal fractionation trends and are interpreted as the result of new
magma influxes into a continuously replenished magma chamber. Basal layers have decoupled Cu and PGE peaks reflecting increasing
PGE tenors up-section, due to increasing R factors during the replenishment episode, or progressive mixing of between resident PGE-poor magma and more PGE-enriched
replenishing magma. The presence of PGE enriched sulfides in cumulates from a lamprophyric magma implies that low-degree partial
melts do not necessarily leave sulfides and PGEs in the mantle restite during partial melting.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
42.
43.
文章通过详细的野外地质调查和系统的岩石化学、稀土元素、微量元素及硅、氧同位素等研究,探讨了羊蹄子山-磨石山钛矿区无矿白色硅质岩和富钛硅质岩的成因及形成地质构造环境。研究结果表明,呈厚层状产出的无矿白色硅质岩具较高的SiO2、Al2O3含量及Al/(Al Fe Mn)、Al2O3/(Al2O3 Fe2O3)比值,稀土元素总量很低,其北美页岩标准化配分模式为向右倾的曲线,无明显铈异常和铕异常,表明其形成于受陆源影响的大陆边缘构造环境;赋矿岩系中薄层状富钛硅质岩的TiO2、Fe2O3、Cu、V含量较高,但Al/(Al Fe Mn)、Al2O3/(Al2O3 Fe2O3)比值较低,稀土元素总量较高,北美页岩标准化曲线为明显左倾型-平坦型,具弱的负铈异常,表明其形成于洋脊及附近环境。两种硅质岩的δ30Si值为变化较小的负值,与热水沉积和某些生物成因硅质岩的硅同位素组成相似,两者的δ18O值范围和平均值均相似。两类硅质岩的成因及形成构造环境不同,富钛硅质岩的地球化学特征表明,该矿床的形成与本区元古宙海底火山热液喷流作用有关。 相似文献
44.
Trace elements contamination of agricultural soils affected by sulphide exploitation (Iberian Pyrite Belt,Sw Spain) 总被引:1,自引:0,他引:1
Agricultural soils of the Riotinto mining area (Iberian Pyrite Belt) have been studied to assess the degree of pollution by
trace elements as a consequence of the extraction and treatment of sulphides. Fifteen soil samples were collected and analysed
by ICP-OES and INAA for 51 elements. Chemical analyses showed an As–Cu–Pb–Zn association related with the mineralisation of
the Iberian Pyrite Belt. Concentrations were 19–994 mg kg−1 for As, 41–4,890 mg kg−1 for Pb, 95–897 mg kg−1 for Zn and of 27–1,160 mg kg−1 for Cu. Most of the samples displayed concentrations of these elements higher than the 90th percentile of the corresponding
geological dominium, which suggests an anthropogenic input besides the bedrock influence. Samples collected from sediments
were more contaminated than leptosols because they were polluted by leachates or by mining spills coming from the waste rock
piles. The weathering of the bedrock is responsible for high concentrations in Co, Cr and Ni, but an anthropogenic input,
such as wind-blown dust, seems to be indicative of the high content of As, Cu, Pb and Zn in leptosols. The metal partitioning
patterns show that most trace elements are associated with Fe amorphous oxy-hydroxides, or take part of the residual fraction.
According to the results obtained, the following mobility sequence is proposed for major and minor elements: Mn, Pb, Cd, > Zn,
Cu > Ni > As > Fe > Cr. The high mobility of Pb, Cu and Zn involve an environmental risk in this area, even in soils where
the concentrations are not so high. 相似文献
45.
Eleven surface soil samples from calcareous soils of industrial areas in Hamadan Province, western Iran were analyzed for
total concentrations of Zn, Cd, Ni, Cu and Pb and were sequentially extracted into six fractions to determine the bioavailability
of various heavy metal forms. Total Zn, Cd, Ni, Cu and Pb concentrations of the contaminated soils were 658 (57–5,803), 125.8
(1.18–1,361), 45.6 (30.7–64.4), 29.7 (11.7–83.5) and 2,419 (66–24,850) mg kg−1, respectively. The soils were polluted with Zn, Pb, and Cu to some extent and heavily polluted with Cd. Nickel values were
not above regulatory limits. Copper existed in soil mainly in residual (RES) and organic (OM) fractions (about 42 and 33%,
respectively), whereas Zn occurred essentially as RES fraction (about 69%). The considerable presence of Cd (30.8%) and Pb
(39%) in the CARB fraction suggests these elements have high potential biavailability and leachability in soils from contaminated
soils. The mobile and bioavailable (EXCH and CARB) fractions of Zn, Cd, Ni, Cu, and Pb in contaminated soils averaged (7.3,
40.4, 16, 12.9 and 40.8%), respectively, which suggests that the mobility and bioavailability of the five metals probably
decline in the following order: Cd = Pb > Ni > Cu > Zn. 相似文献
46.
Concentrations of trace elements and heavy metals (Al, As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Se, Sr, V and Zn) in
the Danjiangkou Reservoir, the water source area of the Middle Route of China’s interbasin South to North Water Transfer Project,
were analyzed using an Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) and compared with the national and
international standards for drinking water. The results indicated that concentrations of As, Pb, Sb and Se in the Reservoir
exceeded the standards and they would pose health risk for residents in the region and the water receiving areas of the interbasin
water transfer project. Spatial and temporal variability of the trace elements and heavy metals in the Reservoir implies their
mixed sources of natural processing and anthropogenic activities in the upper drainage of the Reservoir. The research results
would help develop water resource management and conservation strategy for the interbasin water transfer project. 相似文献
47.
The aim of this interdisciplinary study is to examine a component of the hydrological cycle in Galapagos by characterizing
soil properties. Nine soil profiles were sampled on two islands. Their physical and hydrodynamic properties were analyzed,
along with their mineralogical composition. Two groups of soils were identified, with major differences between them. The
first group consists of soils located in the highlands (>350 m a.s.l.), characterized by low hydraulic conductivity (<10−5 m s−1) and low porosity (<25%). These soils are thick (several meters) and homogeneous without coarse components. Their clay fraction
is considerable and dominated by gibbsite. The second group includes soils located in the low parts of the islands (<300 m
a.s.l.). These soils are characterized by high hydraulic conductivity (>10−3 m s−1) and high porosity (>35%). The structure of these soils is heterogeneous and includes coarse materials. The physical properties
of the soils are in good agreement with the variations of the rainfall according to the elevation, which appears as the main
factor controlling the soil development. The clayey alteration products constrain soils physical and hydrodynamic properties
by reducing the porosity and consequently the permeability and also by increasing water retention. 相似文献
48.
The distribution of several minor and trace elements mainly in fresh (dominating TDS 160–400 mg/l) groundwater of Latvia have
been investigated by the Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) technique. An evaluation of results of about
700 analyses leads to the conclusion that concentrations of these elements is influenced by: pH–Eh conditions, groundwater
residence time and diffuse contamination, whereas the role of water-bearing sediments is of secondary importance. Most trace
elements are characterised by low mobility under alkaline and reducing conditions; concentrations in confined aquifers are
much smaller than the Maximum Permissible Values for drinking water. The strongest anomalies of REE, Al and P were found in
shallow groundwater around the former agrochemical storehouses. 相似文献
49.
苏北盘石山、练山地幔捕虏体的PGE地球化学 总被引:3,自引:0,他引:3
通过锍镍火试金预富集法,分析了位于郯庐断裂带东侧的盘石山、练山地幔橄榄岩包体中铂族元素(PGE)和Au含量.不同于部分熔融残留成因地幔橄榄岩中通常所观察到的负斜率型或平坦型的分布模式,这两地的地幔橄榄岩以Pt、Pd、Ru相对富集,Ir、Rh相对亏损的"燕子型"分布模式为特征.Pt、Pd等不相容元素富集说明上地幔除经历过早期的部分熔融外,还经历了后期富Pt、Pd的高熔/岩比的熔(流)体的层析分离交代作用影响.盘石山地幔橄榄岩的PGE总量比练山高,Os的含量也比原始地幔值高;而练山地幔橄榄岩的Os含量比原始地幔值低,说明交代作用带走了练山地幔橄榄岩中的Os,却没有很大改变盘石山地幔橄榄岩中的Os含量,这可能与交代熔(流)体含硫量饱和程度有关.Rh的负异常可能与部分熔融过程中熔体较低的fo2有关. 相似文献
50.
Mihoko Hoshino Mitsuyoshi Kimata Norimasa Nishida Masahiro Shimizu 《Physics and Chemistry of Minerals》2008,35(2):59-70
Dissakisites from Trimouns dolomite mine, France, have two kinds of single crystals: chemical-zoned and homogeneous types.
Back-scattered electron microprobe (BSE) images of these dissakisites reveal both Ca–Al rich dark zones and Fe-ΣREE rich bright
zones. Crystal structures of three dark and two bright zones in a chemical-zoned dissakisite and of a homogeneous zone in
unzoned dissakisite were refined to individual R indices (about 3.0–5.0%) based on 1,400 observed [|F
0| > 4σF
0] reflections measured with MoKα X-radiation using the single crystal diffractometer. The differences in brightness between
their BSE images arise from those in coupled substitutions of the elements occupying A2 and M3 sites. The main reason for
these differences is that ten-coordinated A2 polyhedra and M3 octahedra are directly linked through their shared edge, which
creates a great potential for making this coupled substitution. This zoning indicates that formation of the whole zoned crystal,
where each zone could be grown steadily with its crystallographic axes mutually parallel to each other, may be identified
as autoepitaxy. 相似文献